High Concentration Doping of Semiconductors by Deposition of Encapsulated Dopant Solid Diffusion Source

Optical, electrical, or electro-optical devices (HFETs, LD, and LEDs)Germanium light emitters  

Problem Addressed 

Some doping methods such as ion implantation, severely damage the lattice of the semiconductor material and this damage worsens device performance. The standard methods used to correct the lattice damage often reverse the deposition process itself by allowing the dopants to diffuse out of the film.  

Technology

The deposition process is completed in two steps. First, a solid state diffusion source is deposited on the surface of the film in alternating layers of the dopant and an encapsulating semi conductor. Second, after removing the substrate from the reactor, an anneal is performed to drive in the dopants by diffusion from the source layer into and throughout the semiconductor film. A possible third step consists of removing the encapsulating material of the diffusion source. What results is a single highly doped semi conductor film, without any defects caused by introducing dopants beyond the In-situ limit. the lattice damage which is standard to doping.  

Advantages      

  • In-situ doping minimizes damage from externally adding dopants to semiconductor and thus maintains lattice structure and a high fraction of activated dopants  

Researchers

Rodolfo Camacho-Aguilera / Jonathan Bessette / Yan Cai / Lionel Kimerling / Jurgen Michel / Jifeng Liu

Departments: Department of Materials Science and Engineering, Materials Research Laboratory
Technology Areas: Communication Systems: Optical / Electronics & Photonics: Photonics, Semiconductors

  • high-concentration active doping in semiconductors and semiconductor devices produced by such doping
    United States of America | Granted | 9,692,209
  • method for high-concentration doping of germanium with phosphorus
    United States of America | Granted | 10,680,413

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